| Christian Clavier | Napoléon Bonaparte [L] | |
| Gérard Depardieu | Joseph Fouché [L] | |
| Isabella Rossellini | Joséphine de Beauharnais [L] | |
| John Malkovich | Talleyrand [L] | |
| Anouk Aimée | Letitia Bonaparte [SR] | |
| Heino Ferch | Armand Augustin Louis, Marquis de Caulaincourt [SR] | |
| Sebastian Koch | Jean Lannes [SR] | |
| Ennio Fantastichini | Joseph Bonaparte [SR] | |
| Guillaume Depardieu | Muiron [SR] | |
| Julian Sands | Klemens von Metternich [SR] | |
| Toby Stephens | Tsar Alexander I [SR] | |
| John Wood | Pope Pius VII [SR] | |
| Marie Bäumer | Caroline Bonaparte [SR] | |
| Claudio Amendola | Murat [SR] | |
| Mavie Hörbiger | Marie Louise of Austria [SR] | |
| Natacha Amal | Madame Bertrand [SR] | |
| Fabienne Babe | Madame de Staël [SR] | |
| André Chaumeau | Louis XVIII [SR] | |
| Constance Dollé | Pauline [SR] | |
| Alain Doutey | Maréchal Ney [SR] | |
| Serge Dupire | Cambronne [SR] | |
| Tamsin Egerton | Betzy [SR] | |
| Vincent Grass | Charles IV of Spain [SR] | |
| Christopher Heyerdahl | Geoffroy St-Hilaire [SR] | |
| Yves Jacques | Lucien Bonaparte [SR] | |
| Alexandra Maria Lara | Marie Walewska [SR] | |
| Jacky Nercessian | Roustam [SR] | |
| Florence Pernel | Madame Tallien [SR] | |
| Ludivine Sagnier | Hortense de Beauharnais [SR] | |
| Charlotte Valandrey | Madame Coigny [SR] | |
| Philippe Volter | Barras [SR] | |
